A macrocyclic 'Co0' complex: The relevance of ligand non-innocence to reactivity

Manuel Kaspar, Philipp J. Altmann, Alexander Pöthig, Stephen Sproules, Corinna R. Hess

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

10 Zitate (Scopus)

Abstract

We present a formally zero-valent compound, [Co(Mabiq)Na(OEt2)]2 (1). The complex was characterized by crystallographic, spectroscopic and DFT computational methods. The electronic structure is described as a CoII-(ligand-biradical). Compound 1 is reactive toward proton sources; CoI or CoII products result, depending on the source of protons used. The redox non-innocence of the Mabiq ligand, which accepts both protons and electrons, has important ramifications for reactivity.

OriginalspracheEnglisch
Seiten (von - bis)7282-7285
Seitenumfang4
FachzeitschriftChemical Communications
Jahrgang53
Ausgabenummer53
DOIs
PublikationsstatusVeröffentlicht - 2017

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