18-membered heterometallacyclic gold(I) compounds: Structural influences of Co-crystallized solvent

Liliana Dobrzańska; Christoph E. Strasser; Hubert Schmidbaur; Helgard G. Raubenheimer

doi:10.5560/ZNB.2012-0222

18-membered heterometallacyclic gold(I) compounds: Structural influences of Co-crystallized solvent

Liliana Dobrzańska
, Christoph E. Strasser
, Hubert Schmidbaur
, Helgard G. Raubenheimer

Department Chemistry

Stellenbosch University
Katholieke Universiteit Leuven
Kind AbdulAziz University

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

1 Zitat (Scopus)

Abstract

5-Lithiated 4,4-dimethyl-2-(2-thienyl)oxazoline reacted by halide and tetrahydrothiophene (THT) substitution with [AuCl(THT)] to form a cyclic trinuclear compound (1) in satisfactory yield. Spectroscopic studies and single-crystal X-ray analyses clarified the bonding within the ring system. The structure determination of two THF solvates revealed differences in the supramolecular assembly of the constituting molecules.

Originalsprache	Englisch
Seiten (von - bis)	1115-1122
Seitenumfang	8
Fachzeitschrift	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Jahrgang	67
Ausgabenummer	10
DOIs	https://doi.org/10.5560/ZNB.2012-0222
Publikationsstatus	Veröffentlicht - Okt. 2012

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10.5560/ZNB.2012-0222

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title = "18-membered heterometallacyclic gold(I) compounds: Structural influences of Co-crystallized solvent",

abstract = "5-Lithiated 4,4-dimethyl-2-(2-thienyl)oxazoline reacted by halide and tetrahydrothiophene (THT) substitution with [AuCl(THT)] to form a cyclic trinuclear compound (1) in satisfactory yield. Spectroscopic studies and single-crystal X-ray analyses clarified the bonding within the ring system. The structure determination of two THF solvates revealed differences in the supramolecular assembly of the constituting molecules.",

keywords = "Carbene character, Crystal modification, Gold, Heterometallacylic complexes, Thienyl oxazoline",

author = "Liliana Dobrza{\'n}ska and Strasser, \{Christoph E.\} and Hubert Schmidbaur and Raubenheimer, \{Helgard G.\}",

year = "2012",

month = oct,

doi = "10.5560/ZNB.2012-0222",

language = "English",

volume = "67",

pages = "1115--1122",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

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TY - JOUR

T1 - 18-membered heterometallacyclic gold(I) compounds

T2 - Structural influences of Co-crystallized solvent

AU - Dobrzańska, Liliana

AU - Strasser, Christoph E.

AU - Schmidbaur, Hubert

AU - Raubenheimer, Helgard G.

PY - 2012/10

Y1 - 2012/10

N2 - 5-Lithiated 4,4-dimethyl-2-(2-thienyl)oxazoline reacted by halide and tetrahydrothiophene (THT) substitution with [AuCl(THT)] to form a cyclic trinuclear compound (1) in satisfactory yield. Spectroscopic studies and single-crystal X-ray analyses clarified the bonding within the ring system. The structure determination of two THF solvates revealed differences in the supramolecular assembly of the constituting molecules.

AB - 5-Lithiated 4,4-dimethyl-2-(2-thienyl)oxazoline reacted by halide and tetrahydrothiophene (THT) substitution with [AuCl(THT)] to form a cyclic trinuclear compound (1) in satisfactory yield. Spectroscopic studies and single-crystal X-ray analyses clarified the bonding within the ring system. The structure determination of two THF solvates revealed differences in the supramolecular assembly of the constituting molecules.

KW - Carbene character

KW - Crystal modification

KW - Gold

KW - Heterometallacylic complexes

KW - Thienyl oxazoline

UR - https://www.scopus.com/pages/publications/84867962669

U2 - 10.5560/ZNB.2012-0222

DO - 10.5560/ZNB.2012-0222

M3 - Article

AN - SCOPUS:84867962669

SN - 0932-0776

VL - 67

SP - 1115

EP - 1122

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 10

ER -

18-membered heterometallacyclic gold(I) compounds: Structural influences of Co-crystallized solvent

Abstract

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